Biopolym. Cell. 1997; 13(5):372-376.
http://dx.doi.org/10.7124/bc.000498
Structure and Function of Biopolymers
The dielectric friction influence on character of temperature dependence of the rate enzyme reactions
1Danchuk V. D.
  1. Ukrainian Transport University
    1, Suvorova Str., Kyiv, Ukraine, 01010

Abstract

The evident dependence of dielectric friction coefficient from translational vibrations frequency of dipole and temperature is obtained by the dielectric continuum theory. The dipole is activated enzyme substrate complex model here. !t is found that the anomalous (non Arrhenius) temperature dependence of the rate enzyme reactions can be occurred owing of resonance dissipation energy dipole in dielectric friction presence. The results of the calculations are agree with experiment qualitatively.
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