Biopolymers and cell. 1997; 13 (5): 372 - 376

The dielectric friction influence on character of temperature dependence of the rate enzyme reactions

V. D. Danchuk

The evident dependence of dielectric friction coefficient from translational vibrations frequency of dipole and temperature is obtained by the dielectric continuum theory. The dipole is activated enzyme substrate complex model here. !t is found that the ano¬malous (non Arrhenius) temperature dependence of the rate enzyme reactions can be occured owing of resonance dissipation energy dipole in dielectric friction presence. The results of the calculations are agree with experiment qualitatively.